Other villages' leaders or powerful ninjas who don't believe Naruto is ready to be a Kage. They might try to test him or even plot against him during diplomatic meetings before the summit, seeing his new position as a potential weakness in the balance of power.
In this fanfiction, perhaps Naruto becoming a Kage before the summit means he has to face political challenges early on. He might have to deal with other villages' representatives who are skeptical of his young age and inexperience. He could use his unique ninja way and his strong bonds with his friends to win them over.
Naruto could still be the main character. As the Hokage, he would be at the center of the Kage Summit. His ideals of peace and unity would play a major role in the interactions with the other Kages. He might try to convince the other Kages to support a new initiative for a more united ninja world.
It could be a rogue ninja who has a vendetta against all the villages represented at the summit. He might have been wronged in the past by the combined actions of the five great villages and now seeks revenge. He could use the chaos of the summit to launch attacks and try to undermine the stability of the shinobi world.
A new, young ninja from a minor village could be the main character. They could be trying to make a name for themselves and their village at the Kage Summit. They might get involved in some political intrigue or even a fight between the Kages and prove their worth.
Sasuke could be one to stop Naruto. They have a complex relationship and Sasuke might understand Naruto's motives and be able to talk him down.
The Kages themselves are often main characters. For example, Tsunade from Konoha, Gaara from Suna, and the other village leaders. They play important roles in the political and power - related discussions during the summit.
Gaara could be one of his potential allies. Since they have a history together and Gaara has changed a lot, he might support Naruto. Also, the Raikage might become an ally if Naruto can prove that his intentions are good for the entire ninja world.
It could be Naruto himself. Since he has a connection to all the villages in some way, he could play a crucial role in the fanfic, perhaps as a mediator or someone who uncovers a hidden conspiracy during the summit.
Obviously Naruto would be one of the main characters as the title implies he's the one attacking. And the Kages, like Gaara, Tsunade, and the other village leaders would also be main characters since they are at the summit that Naruto is attacking.
Perhaps in the fanfiction, there are internal power struggles within the villages that are revealed at the Kage Summit. A young ninja from one of the villages might try to influence the decisions of their Kage during the summit. There could also be a cultural exchange aspect, where the Kages learn about each other's villages' traditions and find ways to incorporate beneficial elements into their own villages.