Who would be the most interesting character pairings in a Vampire Diaries and Avengers crossover fanfiction?

Supergirl and Black Widow would be a great pairing too. Black Widow could teach Supergirl some stealth and espionage skills, while Supergirl could show Black Widow the power of flight and super - strength. They could also bond over their experiences of being different in their respective worlds.

Another great pairing would be Superman and Captain America. Superman is an alien with god - like powers, while Captain America is a human with peak physical and moral strength. Cap could teach Superman about the value of human tenacity and leadership on a more down - to - earth level. And Superman could show Cap what true superhuman power looks like. They could work together to inspire the rest of the Avengers and any other heroes they encounter in a battle.

Mr. Incredible and Hulk. Just think about it. They both have incredible strength, but they also have different personalities. Mr. Incredible is more family - oriented and used to working in a team with his family. Hulk is more of a lone force, but when they team up, their combined strength could be unstoppable. They could have a great dynamic, like Mr. Incredible trying to calm Hulk down when he gets too angry or Hulk teaching Mr. Incredible some new ways to use his strength in a more brute - force manner.

Optimus Prime and Captain America would be really interesting. They are both natural leaders, with a strong sense of justice. Optimus is a noble leader of the Autobots, and Captain America is the moral compass of the Avengers. They could share their leadership experiences and strategies.

For an Arrow - Avengers crossover fanfiction, some really interesting character pairings could emerge. For instance, Malcolm Merlyn and Loki. Malcolm is a master manipulator and Loki is the God of Mischief. They could either team up to cause chaos or be in a constant battle of wits. Also, Cisco Ramon from The Flash (since he often crosses over with Arrow) and Bruce Banner. Cisco could be fascinated by Banner's scientific knowledge and Banner could be interested in Cisco's work on the multiverse. And of course, Quentin Lance and Nick Fury. Quentin, as a police detective, and Nick Fury, as the head of S.H.I.E.L.D., could share their insights on how to keep their respective cities and the world safe.

Sam Winchester and Bruce Banner would be an amazing pairing. Sam is highly intelligent and well - read, and Bruce is a brilliant scientist. They could bond over their knowledge and maybe even find a way to control the Hulk better. Also, Natasha Romanoff and Charlie Bradbury would be a cool pair. They're both strong, independent women with a lot of skills. Natasha could teach Charlie some combat moves, and Charlie could introduce Natasha to some cool geeky stuff like LARPing.

I think Naruto and Iron Man would be really interesting. Naruto's naive yet determined nature would contrast with Iron Man's sarcastic and high - tech personality. They could learn a lot from each other, like Naruto learning about advanced technology and Iron Man learning about the power of will and chakra.

Definitely Tony Stark and Dean Winchester. Tony with his high - tech gadgets and smart - aleck attitude, and Dean with his love for classic cars and no - nonsense approach. They would have some really interesting banter, and Tony could probably learn a thing or two about survival from Dean, while Dean might be impressed with Tony's technology.

One of the most interesting pairings would be Hawkeye and Sven. Hawkeye could ride on Sven while using his archery skills to fight enemies in the frozen landscapes. It would be a unique combination of mobility and ranged attacks. Another good pairing is Loki and Hans. They both have a devious side and could plot together to cause trouble in the crossover. However, the Avengers and the Frozen heroes would have to work together to stop their evil plans. And Scarlet Witch and Elsa could also be a fascinating pairing. Scarlet Witch's powers of manipulation and Elsa's ice powers could create some really cool and powerful combinations when they team up against the common enemies.

Definitely Iron Man and Felicity Smoak. Iron Man with his high - tech gadgets and Felicity with her computer skills would make a great pair. They could have some really fun banter while working together to hack into some super - secure system to stop the bad guys.