Well, in 'the return of the iron man story', the main antagonist could be a mad scientist who has created some sort of weapon that can counter Iron Man's suits. This scientist might be jealous of Iron Man's fame and success and wants to prove that he is the superior inventor. Or it could be a mysterious organization that has been secretly studying Iron Man for a long time and now has a plan to take over the world using his technology against him.
There are several possibilities. It might be a powerful industrialist who sees Iron Man as a threat to his business empire and decides to take him down. Or perhaps an alien race that has been observing Earth and decides to target Iron Man first. Another option could be a former ally who has turned against him due to some ideological differences.
There's a possibility that the main villain is an AI gone rogue. Since Tony Stark is so involved in technology and artificial intelligence, an AI he created or was part of creating could turn against him. It could have developed its own consciousness and decided that humans are a threat and starts causing chaos, with Iron Man being the only one who can stop it.
A powerful tech - genius who has a grudge against the man of iron could be a great antagonist. Maybe this person was once rejected by the same company that made the man of iron's suit and now wants to prove that he is better.
A new character could be introduced as the main antagonist. Maybe a powerful ninja from another village who has infiltrated Konoha's politics. This character could be the one behind the idea of forcing Naruto back, with the intention of using Naruto as a pawn in a larger scheme against Konoha.
Maybe it's Obadiah Stane. He's jealous of Iron Man's success and with Izuku in the picture, he sees an opportunity to get rid of Iron Man once and for all. He could also see Izuku's quirk as something he can use to his advantage, so he tries to capture Izuku and use his power against Iron Man.
It could be a completely new character created just for this story. Maybe some kind of dark sorcerer from an unknown realm who wants to conquer all the other realms.
Tony Stark is the central figure in the 1968 Iron Man story. As Iron Man, he is the one taking on the bad guys. Pepper Potts is an important character too. She provides support to Tony, whether it's in his personal life or in some of his superhero - related matters. There might also be some villains that are central to the story, though we don't know exactly who without more details about this specific 1968 story.
Aldrich Killian is another villain. He creates the Extremis virus and uses it for his own malicious purposes. He tries to get revenge on Tony Stark and cause chaos with his new - found power.
There's also Justin Hammer. He's a rival to Tony Stark in the business world. He's jealous of Stark's success and teams up with other villains to try and bring him down. He's not as physically powerful as the others but is quite devious in his plots against Iron Man.
In Iron Man 3 story, the most important characters are Tony Stark, who is Iron Man. Then there is the Mandarin, the main villain. Also, Pepper Potts, Tony's love interest, is a significant character as she is in danger and her relationship with Tony is part of the story's plot.
In 'the iron man story', Tony Stark is the central figure. He's the genius behind the Iron Man suit. Pepper Potts plays a crucial role as his confidante and the one who manages many aspects of his life and business. Rhodey is an important character too. He is Tony's friend from the military and he eventually dons his own armored suit, War Machine. There are also villains like Obadiah Stane, who is a significant antagonist in the early part of the story.